Cerium Oxalate Powder Chemical Reagent Elements
Détails de produit
| Abondance dans la croûte terrestre: | 0,001% à 0,02% | Couleur: | Blanc argenté à gris |
|---|---|---|---|
| Potentiel de recyclage: | Élevé, en raison de problèmes d’approvisionnement critiques | Groupe d'éléments: | lanthanides |
| Impact environnemental: | Potentiellement élevé s’il n’est pas géré correctement | boilingPoint: | 1464°C à 3507°C (varie selon l'élément) |
| Conductivité électrique: | Modéré à élevé | Nom du produit: | matériel de terre rare |
| État physique: | Solide | Densité: | 6,15 à 9,84 g/cm³ (varie selon l'élément) |
| Points communs: | Electronique, aimants, catalyseurs, batteries | Propriétés magnétiques: | Paramagnétique ou ferromagnétique selon l'élément |
| Méthode d'extraction: | Extraction minière et par solvant | Point de fusion: | 798°C à 1527°C (varie selon l'élément) |
| catégorie: | Éléments chimiques | ||
| Mettre en évidence |
Cerium Oxalate chemical reagent,Rare Earth Oxalate powder,Cerium Oxalate lab compound |
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Description de produit
1. Basic Information
- Chinese Name: Cerium Oxalate, Cerous Oxalate
- English Name: Cerium(III) oxalate, Cerous oxalate
- Chemical Formula: (usually hydrate, where x is mostly 9 or 10)
- Molecular Weight (Anhydrous): 544.29
- CAS No.:
- Anhydrous: 139-42-4
- Hydrate: 15750-47-7
2. Physical and Chemical Properties
- Appearance: White or pale yellow crystalline powder, odorless and tasteless.
- Solubility: Practically insoluble in water, insoluble in ethanol, diethyl ether, oxalic acid solution and alkaline solution; but soluble in hot dilute hydrochloric acid and dilute sulfuric acid.
- Thermal Stability: Easily decomposes upon heating, first losing crystal water; further high-temperature calcination leads to decomposition into cerium dioxide (), carbon monoxide and carbon dioxide.
- Chemical Characteristics: Chemically stable, cerium exists in +3 valence state with weak oxidizing property.
3. Preparation Method
- Use trivalent cerium salt solutions (such as cerium nitrate or cerium chloride ) as raw materials.
- Add oxalic acid () or ammonium oxalate solution as precipitant.
- Control the pH value to precipitate cerium(III) oxalate, which is then obtained after washing and drying.
4. Main Applications
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Preparation of High-Purity Cerium OxideAs the most important precursor, cerium(III) oxalate can be calcined at high temperature to produce high-purity and high-activity cerium dioxide (), which is widely used in automotive exhaust catalysts, polishing powders, fuel cells, etc.
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Rare Earth SeparationBased on its poor solubility, cerium is precipitated and separated from mixed rare earth solutions to achieve preliminary separation from other rare earth elements.
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Pharmaceutical FieldHistorically used as an antiemetic for the treatment of morning sickness and gastrointestinal discomfort, and also has the effects of invigorating the stomach and sedation.
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Chemical ReagentUsed as an analytical reagent and raw material for the synthesis of other cerium compounds.
5. Safety and Storage
- Safety: Toxic and irritating substance. Avoid ingestion, inhalation or contact with skin and mucous membranes.
- Storage: Keep sealed, dry and stored in a cool place.
Cerium Oxalate
Molecular Formula: Ce₂(C₂O₄)₃
Appearance: Cerium oxalate is a white crystalline powder
Application: Used as a chemical reagent and for the preparation of other cerium salts
|
Item |
Specification |
Testing Standard |
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|
Item |
Ce2(C2O4)3-3N5 |
Ce2(C2O4)3-4N |
Ce2(C2O4)3-4N5 |
Ce2(C2O4)3-5N |
|
|
TREO(wt%) |
≥38 |
≥38 |
≥38 |
≥38 |
|
|
Rare Earth Relative Purity (wt%) |
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|
La2O3/TREO |
≤0.01 |
≤0.005 |
≤0.003 |
≤0.0004 |
GB/T 18115.2 |
|
CeO2/TREO |
≥99.95 |
≥99.99 |
≤99.995 |
≥99.999 |
|
|
Pr6O11/TREO |
≤0.01 |
≤0.002 |
≤0.001 |
≤0.0002 |
|
|
Nd2O3/TREO |
≤0.01 |
≤0.002 |
≤0.001 |
≤0.0002 |
|
|
Sm2O3/TREO |
≤0.001 |
≤0.0005 |
≤0.0002 |
≤0.0001 |
|
|
Y2O3/TREO |
≤0.001 |
≤0.0005 |
≤0.0002 |
≤0.0001 |
|
|
Non-Rare Earth Impurities Content (wt%) |
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|
Fe2O3 |
≤0.002 |
≤0.0015 |
≤0.001 |
≤0.001 |
GB/T 12690 |
|
CaO |
≤0.01 |
≤0.005 |
≤0.003 |
≤0.003 |
|
|
MgO |
≤0.002 |
≤0.001 |
≤0.0005 |
≤0.0005 |
|
|
SiO2 |
≤0.01 |
≤0.005 |
≤0.003 |
≤0.003 |
|
|
ZnO |
≤0.001 |
≤0.001 |
≤0.001 |
≤0.001 |
|
|
Na2O |
≤0.005 |
≤0.002 |
≤0.002 |
≤0.002 |
|
|
PbO |
≤0.005 |
≤0.003 |
≤0.002 |
≤0.002 |
|
|
SO42- |
≤0.03 |
≤0.03 |
≤0.03 |
≤0.03 |
|
|
Cl- |
≤0.07 |
≤0.07 |
≤0.05 |
≤0.05 |
|
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Note: Cerium oxalate is insoluble in water. Packaging: This product is usually packed in 50kg or 1000kg, and can also be packed according to customer requirements. The packaging material is a woven bag lined with a plastic bag. |
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Points forts du produit
Cerium oxalate is an oxalate salt of trivalent cerium and an important rare earth compound, often existing in the form of hydrate. 1. Basic Information Chinese Name: Cerium Oxalate, Cerous Oxalate English Name: Cerium(III) oxalate, Cerous oxalate Chemical Formula: (usually hydrate, where x is mostly ...
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